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- "A rematch would be good, but without stakes this time..."
- ―Chiyo to Shiho
Chiyo is a member of the Japanese Sensha-dō Federation.
Chiyo is a beautiful woman with long light brown hair tied with a black ribbon and a pair of hazel eyes. Her appearance is a lot less cold than Shiho and seems to be much nicer. She has very pale skin and bears a striking resemblance to her daughter.
Chiyo is a very calm and refined woman. She seems very intelligent and is willing to be the best, going to great lengths just to beat her rival. When she calls Alice just before the match against the All-Stars University Team, she tells her to destroy the name of Nishizumi style. However, despite this behaviour, she's not a bad person and loves her daughter more than anything else as she still sponsors the Boko Museum despite her daughter's losing. She tends, however, to have trouble accepting Alice is growing up.
- The Shimada family is mentioned by Anchovy right before the match against Ooarai Girls Academy on the Anzio OVA.
- Nicknamed Chiyokichi by Shiho Nishizumi in MLLSD. It's implied that they've been friends for a long time.
- Main article: Chiyo Shimada/Gallery
|Ooarai Girls High School||Anglerfish Team||Miho Nishizumi ♦ Saori Takebe ♦ Hana Isuzu ♦ Yukari Akiyama ♦ Mako Reizei|
|Duck Team||Noriko Isobe ♦ Taeko Kondou ♦ Shinobu Kawanishi ♦ Akebi Sasaki|
|Hippo Team||Erwin ♦ Caesar ♦ Saemonza ♦ Oryou|
|Rabbit Team||Azusa Sawa ♦ Aya Oono ♦ Ayumi Yamagou ♦ Yuuki Utsugi ♦ Karina Sakaguchi ♦ Saki Maruyama|
|Turtle Team||Anzu Kadotani ♦ Momo Kawashima ♦ Yuzu Koyama|
|Mallard Team||Midoriko Sono ♦ Moyoko Gotou ♦ Nozomi Konparu|
|Leopon Team||Satoko Nakajima ♦ Hoshino ♦ Suzuki ♦ Tsuchiya|
|Anteater Team||Nekota ♦ Momoga ♦ Piyotan|
|Shark Team||Ogin ♦ Murakami ♦ Cutlass ♦ Flint ♦ Rum|
|Miscellanous||Taiga Ou ♦ Sadoka ♦ Mazoe|
|St. Gloriana Girls High School||Darjeeling ♦ Orange Pekoe ♦ Assam ♦ Rosehip ♦ Rukuriri ♦ Nilgiri ♦ Vanilla ♦ Cranberry ♦ Earl Grey|
|Saunders Girls High School||Kay ♦ Alisa ♦ Naomi ♦ Helmet-Chan|
|Anzio Girls High School||Anchovy ♦ Carpaccio ♦ Pepperoni ♦ Amaretto ♦ Gelato ♦ Panettone|
|Pravda Girls High School||Katyusha ♦ Nonna ♦ Klara ♦ Nina ♦ Alina|
|Kuromorimine Girls High School||Maho Nishizumi ♦ Erika Itsumi ♦ Koume Akaboshi ♦ Leila Rou ♦ Emi Kojima ♦ Geshiko ♦ Sangou ♦ Mauko ♦ Sheska|
|Chi-Ha-Tan Academy||Kinuyo Nishi ♦ Fukuda ♦ Haru Tamada ♦ Hosomi ♦ Nagura ♦ Hamada ♦ Teramoto ♦ Ikeda|
|Jatkosota High School||Mika ♦ Aki ♦ Mikko ♦ Touko ♦ Lili|
|BC Freedom High School||Ribbon Warrior||Asparagus ♦ Moules ♦ Bordeaux|
|Das Finale||Marie ♦ Andou ♦ Oshida|
|Tatenashi Girls High School||Shizuka Tsuruki ♦ Rin Matsukaze ♦ Haruka Endou|
|Bonple High School||Jajka ♦ Uszka|
|Maginot Girls Academy||Éclair ♦ Fondue ♦ Galette ♦ Madeleine ♦ Colombier|
|Count High School||Noemi Kohiyama ♦ Anna Masukura ♦ Nachigami Sisters ♦ Marina Constantinescu|
|Tategoto High School||Aung|
|Maple High School||Trout ♦ Amber ♦ Oleo|
|Kebab High School||Bosphorus|
|Bellwall Academy||Tiger I Crew||Emi Nakasuga ♦ Hitomi Yuzumoto ♦ Kita ♦ Takami ♦ Nagisa Shiratori|
|Jagdpanther Crew||Neko Yamamori ♦ Yano ♦ Koharu Sakai ♦ Kanbara ♦ Hirono|
|Elefant Crew||Chifuyu Doi ♦ Terauchi ♦ Wakasugi ♦ Kunihiro ♦ Nogata ♦ Enami|
|T-44 Crew||Youko Minami ♦ Saionji ♦ Azuma ♦ Hokuto|
|Panzer II Crew||Kashiwaba Sisters|
|West Kureouji Grona Academy||Kiri Shiratori|
|All-Stars University Team||Alice Shimada ♦ Azumi ♦ Megumi ♦ Rumi|
|Japan Sensha-dō Federation||Ami Chōno ♦ Shiho Nishizumi ♦ Renta Tsuji ♦ Chiyo Shimada ♦ Shichiro Kodama ♦ Kikuyo Idegami ♦ Kanon Sasagawa ♦ Hibiki Inatomi ♦ Remi Takashima|
|Non-Affiliated||Yoshiko Akiyama ♦ Jungorou Akiyama ♦ Hisako Reizei ♦ Shinzaburo ♦ Yuri Isuzu ♦ Chihiro Yusa ♦ Boko|